• Ir/Sn dual-reagent catalysis towards highly selective alkylation of arenes and heteroarenes with benzyl alcohols

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      https://www.ias.ac.in/article/fulltext/jcsc/120/05/0429-0439

    • Keywords

       

      Organometallic; bimetallic; catalysis; alkylation; benzyl alcohol; iridium, tin.

    • Abstract

       

      A catalytic combination of [Ir(COD)Cl]2-SnCl4 efficiently promotes the reactions of arenes and heteroarenes with $1^\circ/2^\circ/3^\circ$ benzyl alcohols as the alkylating agents to afford the corresponding diarylmethane and triarylmethane derivatives in high yields. The scope and limitation of the reaction with respect to catalyst and substrates variation has been studied in detail.

    • Author Affiliations

       

      Sujit Roy1 Susmita Podder1 Joyanta Choudhury1

      1. Organometallics and Catalysis Laboratory, Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302
    • Dates

       
  • Journal of Chemical Sciences | News

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      Posted on July 25, 2019

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