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    • Keywords


      meso-functionalization; unsymmetrical metalloporphyrins; EPR; fluorescence; metal-ligand interaction.

    • Abstract


      The synthesis and characterization of new meso-substituted unsymmetrical metalloporphyrins has been described. A new modified Adler method was used for the synthesis of two unsymmetrical porphyrins. Reactions of these unsymmetrical porphyrins with metal acetates afforded the corresponding metalloporphyrins in high yields with excellent purity. These porphyrins and their metal derivatives were characterized by spectroscopic methods. However, the copper complexes were further studied by ESR spectra and zinc complex by fluorescence spectrum.

    • Author Affiliations


      Babasaheeb P Bandgar1 Pradip B Gujarathi1

      1. Organic Chemistry Research Laboratory, School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded 431 606
    • Dates

  • Journal of Chemical Sciences | News

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