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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/119/05/0417-0422

    • Keywords

       

      Floquet Hamiltonians; contact transformations in NMR; Spin-1 MAS NMR; effective Hamiltonians.

    • Abstract

       

      Contact transformation is an operator transformation method in time-independent perturbation theory which is used successfully in molecular spectroscopy to obtain an effective Hamiltonian. Floquet theory is used to transform the periodic time-dependent Hamiltonian, to a time-independent Floquet Hamiltonian. In this article contact transformation method has been used to get the analytical representation of Floquet Hamiltonian for quadrupolar nuclei with spin 𝐼 = 1 in the presence of an RF field and first order quadrupolar interaction in magic angle spinning NMR experiments. The eigenvalues of contact transformed Hamiltonian as well as Floquet Hamiltonian have been calculated and a comparison is made between the eigenvalues obtained using the two Hamiltonians.

    • Author Affiliations

       

      Manoj Kumar Pandey1 Mangala Sunder Krishnan1

      1. Department of Chemistry, Indian Institute of Technology - Madras, Chennai 600 036

    • Dates

       
      Published
      September 2007
      Manuscript received
      2 July 2007
      Accepted
      22 August 2007

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