When the reactant surface is not in a thermal equilibrium, but in a thermo-coherent state we have derived the rate and discussed about the quantum features of the rate. In the limit of very low and very high temperature the expressions are derived analytically and compared with the case of thermal distribution. We have investigated the dependence of temperature on the rate due to displacement, distortion of the harmonic potential energy surfaces of the reactant and product manifold.
Volume 134, 2022
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