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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/118/06/0569-0573

    • Keywords

       

      Bisphosphinites; bisphosphines; mandelic acid; allylation; palladium and platinum

    • Abstract

       

      Palladium and platinum complexes of bisphosphinites and bisphosphines derived from mandelic acid have been prepared and characterized. Their ability to catalyze allylation of imines with allyltributylstannane has been studied. Bisphophinite complexes of Pd (II) are shown to be ideal and they work best in the presence of one equivalent of water. The near neutral conditions employed make the catalysts suitable for a wide variety of substrates.

    • Author Affiliations

       

      Rakesh Kumar Sharma1 Ashoka G Samuelson1

      1. Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore - 560 012
    • Dates

       
  • Journal of Chemical Sciences | News

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