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    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/118/06/0455-0462

    • Keywords

       

      Organostannoxanes; organotin; multi-ferrocene; multi-porphyrin; phosphonates; pyrazoles

    • Abstract

       

      Phosphonate ligands, [RPO3]2-, are extremely versatile in the assembly of multi-tin and multi-copper architectures. We have used organostannoxane cores for supporting multi-ferrocene and multi-porphyrin peripheries. The copper-metalated multi-porphyrin compound is an excellent reagent for facile cleavage of DNA, even in the absence of a co-oxidant. Reaction oft-BuPO3H2 with Cu(C104)2. 6H2O in the presence of 2-pyridylpyrazole (2-Pypz) leads to the synthesis of a decanuclear copper (II) assembly.

    • Author Affiliations

       

      Vadapalli Chandrasekhar1 Kandasamy Gopal1 Loganathan Nagarajan1 Palani Sasikumar1 Pakkirisamy Thilagar1

      1. Department of Chemistry, Indian Institute of Technology, Kanpur - 208 016

    • Dates

       
      Published
      November 2006

  • Journal of Chemical Sciences | News

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