• Hydrothermal syntheses and single crystal structural characterization of M(H2O)6(OPTA)2 [M = Co(II), Ni(II), Zn(II); OPTA = 1-oxopyridinium-2-thioacetato]

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/118/03/0243-0248

    • Keywords

       

      Hydrothermal; ionic crystals; cobalt; nickel; zinc; 1-oxopyridinium-2-thioacetato

    • Abstract

       

      A new class of compounds of the family M(H2O)6(OPTA)2 (where M = Co(II), Ni(II), and Zn(II); OPTA = 1-oxopyridinium-2-thioacetato) was prepared from the appropriate metal acetates, 1-oxo-pyridinium-2-thioacetic acid (OPTAH), and potassium hydroxide in hydrothermal media and structurally characterized. The structure is constructed from M(H2O)62+ and two anions of OPTAH (C7H6NO3S) linked through hydrogen bonding into an extended network.

    • Author Affiliations

       

      S Kumaresan1 P Ramadevi1 R D Walsh2 A Mcaneny3 C H Lake3

      1. Department of Chemistry, Manonmaniam Sundaranar University, Abishekapatti Tirunelveli - 627 012
      2. Department of Chemistry, University of South Florida, SCA 400, 4202, East Fowler Avenue, Tampa, FL - 33620-5250, USA
      3. Department of Chemistry, Indiana University of Pennsylvania, Indiana, PA - 15701, USA
    • Dates

       
  • Journal of Chemical Sciences | News

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

© 2021-2022 Indian Academy of Sciences, Bengaluru.