• Hydrothermal syntheses and single crystal structural characterization of M(H2O)6(OPTA)2 [M = Co(II), Ni(II), Zn(II); OPTA = 1-oxopyridinium-2-thioacetato]

    • Fulltext


        Click here to view fulltext PDF

      Permanent link:

    • Keywords


      Hydrothermal; ionic crystals; cobalt; nickel; zinc; 1-oxopyridinium-2-thioacetato

    • Abstract


      A new class of compounds of the family M(H2O)6(OPTA)2 (where M = Co(II), Ni(II), and Zn(II); OPTA = 1-oxopyridinium-2-thioacetato) was prepared from the appropriate metal acetates, 1-oxo-pyridinium-2-thioacetic acid (OPTAH), and potassium hydroxide in hydrothermal media and structurally characterized. The structure is constructed from M(H2O)62+ and two anions of OPTAH (C7H6NO3S) linked through hydrogen bonding into an extended network.

    • Author Affiliations


      S Kumaresan1 P Ramadevi1 R D Walsh2 A Mcaneny3 C H Lake3

      1. Department of Chemistry, Manonmaniam Sundaranar University, Abishekapatti Tirunelveli - 627 012
      2. Department of Chemistry, University of South Florida, SCA 400, 4202, East Fowler Avenue, Tampa, FL - 33620-5250, USA
      3. Department of Chemistry, Indiana University of Pennsylvania, Indiana, PA - 15701, USA
    • Dates

  • Journal of Chemical Sciences | News

© 2022-2023 Indian Academy of Sciences, Bengaluru.