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    • Hydrothermal syntheses and single crystal structural characterization of M(H2O)6(OPTA)2 [M = Co(II), Ni(II), Zn(II); OPTA = 1-oxopyridinium-2-thioacetato]

      S Kumaresan P Ramadevi R D Walsh A Mcaneny C H Lake

      Volume 118 Issue 3 May 2006 pp 243-248

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/118/03/0243-0248

    • Keywords

       

      Hydrothermal; ionic crystals; cobalt; nickel; zinc; 1-oxopyridinium-2-thioacetato

    • Abstract

       

      A new class of compounds of the family M(H2O)6(OPTA)2 (where M = Co(II), Ni(II), and Zn(II); OPTA = 1-oxopyridinium-2-thioacetato) was prepared from the appropriate metal acetates, 1-oxo-pyridinium-2-thioacetic acid (OPTAH), and potassium hydroxide in hydrothermal media and structurally characterized. The structure is constructed from M(H2O)62+ and two anions of OPTAH (C7H6NO3S) linked through hydrogen bonding into an extended network.

    • Author Affiliations

       

      S Kumaresan1 P Ramadevi1 R D Walsh2 A Mcaneny3 C H Lake3

      1. Department of Chemistry, Manonmaniam Sundaranar University, Abishekapatti Tirunelveli - 627 012
      2. Department of Chemistry, University of South Florida, SCA 400, 4202, East Fowler Avenue, Tampa, FL - 33620-5250, USA
      3. Department of Chemistry, Indiana University of Pennsylvania, Indiana, PA - 15701, USA

    • Dates

       
      Published
      May 2006
      Manuscript received
      21 September 2005
      Manuscript revised
      22 December 2005

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