Synthesis, spectroscopic characterization and electronic structure of some new Cu(I) carbene complexes
Chinnappan Sivasankar Christina Baskaran Ashoka G Samuelson
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Reaction of oligomeric Cu(I) complexes [Cu(Μ-S-C(=NR)(O-Ar-CH3)]n with Lewis acids gave Cu(I) carbene complexes, which were characterized by1H and13C NMR spectroscopy. Cu(I) carbene complexes could be directly generated from RNCS, Cu(I)-OAr and Lewis acids; this method can be used to prepare Cu(I) carbene complexes with different substitutents on the carbene carbon. The complexes were unreactive towards olefins and do not undergo cyclopropanation. Electronic structure calculations (DFT) show that the charge on the carbene carbon plays an important role in controlling the reactivity of the carbene complex.
Chinnappan Sivasankar1 Christina Baskaran1 Ashoka G Samuelson1
Volume 135, 2023
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