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      https://www.ias.ac.in/article/fulltext/jcsc/118/02/0211-0218

    • Keywords

       

      N,N′-dibenzyl-N,N,N′,N′-tetramethylethylenediammonium dibromide; hydrogen bonding interactions; cyclic dibromide

    • Abstract

       

      The organic diammonium salt N,N′-dibenzyl-N,N,N′,N′-tetramethylethylenediammonium dibromide dihydrate, (dbtmen)Br2.2H2O (1), was prepared by the reaction of N,N,N′,N′-tetramethyl-ethylenediamine (tmen) with benzyl bromide.1 crystallizes in the triclinic space group$$P\bar 1$$ with the following unit cell dimensions for C20H34Br2N2O2 (M = 494.31):a = 8.6672(6) Å,b = 11.7046(8) Å,c = 11.7731(8) Å, α = 76.988(8)°, β = 88.978(8)°, γ= 76.198(8)γ,V= 1129.26(13) Å3, Z=2. Three components, namely the (dbtmen)2+ dication, two bromide anions and two crystal water molecules constitute the structural arrangement of1. H2O molecules are linked to bromide anions via O-H...Br hydrogen bonding interactions resulting in the formation of a four-membered O2Br2 cyclic dibromide. The O2Br2 units and the dications are arranged as alternating layers extending in the crystallographicbc plane. The arrangement of anions and cations may be viewed as a typical lamellar structure. The crystal water molecules can be removed by heating 1 at 140°C and the anhydrous dibromide thus formed can be fully rehydrated as evidenced by IR spectra and X-ray powder patterns.

    • Author Affiliations

       

      Bikshandarkoil R Srinivasan1 Sunder N Dhuri1 Jyoti V Sawant1 Christian Näther2 Wolfgang Bensch2

      1. Department of Chemistry, Goa University PO, Goa - 403 206
      2. Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Olshausenstraße 40, Kiel - D-24098, Germany
    • Dates

       
  • Journal of Chemical Sciences | News

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