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    • Volumetric studies of some amino acids in binary aqueous solutions of MgCl2·6H2O at 288·15, and 308·15 K

      Amalendu Pal Suresh Kumar

      Volume 117 Issue 3 May 2005 pp 267-273

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/117/03/0267-0273

    • Keywords

       

      Amino acids; transfer functions; cosphere overlap model; interaction coefficients

    • Abstract

       

      Densities (ρ) of glycine, L-alanine, and L-valine in aqueous solutions of MgCl2-6H2O (0.1-0.8 mol kg-1) have been measured at 288.15, and 308.15 K. Apparent molar volumes (Vφ), and limiting partial molar volumes (Vφ0) of each amino acid have been calculated. These data were combined with the earlier reportedVφ0 values of glycine, L-alanine, and L-valine in aqueous MgCl2·6H2O solutions at 298.15 K in order to describe the temperature dependence behaviour of partial molar quantities. Group contributions to partial molar volumes have been determined for the amino acids. The trends of transfer volumes (△Vφ0) have been interpreted in terms of solute-cosolute interactions on the basis of a cosphere overlap model. Pair and triplet interaction coefficients have also been calculated from transfer parameters.

    • Author Affiliations

       

      Amalendu Pal1 Suresh Kumar1

      1. Department of Chemistry, Kurukshetra University, Kurukshetra - 136 119, India

    • Dates

       
      Published
      May 2005
      Manuscript received
      10 May 2004
      Manuscript revised
      24 January 2005

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