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      https://www.ias.ac.in/article/fulltext/jcsc/117/03/0235-0238

    • Keywords

       

      Monobasic bidentate; Schiff bases; ruthenium(II) complexes; spectral studies; triphenyl phosphine

    • Abstract

       

      Reactions of ruthenium(II) complexes [RuHX(CO)(EPh3)2(B)] (X = H or Cl; B = EPh3, pyridine (py) or piperidine (pip); E = P or As) with bidentate Schiff base ligands derived by condensingo- hydroxyacetophenone with aniline,o- orp-methylaniline have been carried out. The products were characterized by analytical, IR, electronic and1H-NMR spectral studies and are formulated as [Ru(X)(CO) (L)(EPh3)(B)] (L = Schiff base anion; X = H or Cl; B = EPh3, py or pip; E = P or As). An octahedral structure has been tentatively proposed for the new complexes. The new complexes were tested for their catalytic activities in the oxidation of benzyl alcohol to benzaldehyde.

    • Author Affiliations

       

      P Viswanathamurthi1 R Karvembu2 V Tharaneeswaran2 K Natarajan3

      1. Department of Chemistry, Periyar University, Salem - 636 011, India
      2. Department of Chemistry (PG), Kongunadu Arts and Science College, Coimbatore - 641 029, India
      3. Department of Chemistry, Bharathiar University, Coimbatore - 641 046, India
    • Dates

       
  • Journal of Chemical Sciences | News

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