• Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/117/02/0167-0173

    • Keywords

       

      N-(2′-hydroxyphenyl)pyrrole-2-aldimine; rhodium and iridium complexes; crystal structure; spectral and electrochemical properties

    • Abstract

       

      Reaction of N-(2′-hydroxyphenyl)pyrrole-2-aldimine (H2L) with [M(PPh3)3Cl] (M = Rh, Ir) affords complexes of type [M(PPh3)2(L)Cl]. Structures of both complexes have been determined by X-ray crystallography. In both complexes, the N-(2′-hydroxyphenyl)pyrrole-2-aldimine ligand is coordinated to the metal centre, via dissociation of the acidic protons, as a dianionic tridentate N,N,O-donor. The M(L)Cl fragment constitutes an equatorial plane with the metal at the centre and the two PPh3 ligands occupying axial positions. The complexes are diamagnetic (low-spin d6, S = 0) and show intense MLCT transitions in the visible region. Cyclic voltammetry of the [M(PPh3)2(L)Cl] complexes shows reversible M(III)-M(IV) oxidation near 0·5 V vs SCE and quasi-reversible ligand-centred oxidative response near 1·0 V vs SCE.

    • Author Affiliations

       

      Semanti Basu1 Indrani Pal1 Ray J Butcher2 Georgina Rosair3 Samaresh Bhattacharya1

      1. Department of Chemistry, Inorganic Chemistry Section, Jadavpur University, Kolkata - 700 032, India
      2. Department of Chemistry, Howard University, Washington DC - 20059, USA
      3. School of Engineering & Physical Sciences - Chemistry, Heriot-Watt University, Edinburgh - EH14 4AS, UK
    • Dates

       
  • Journal of Chemical Sciences | News

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

© 2017-2019 Indian Academy of Sciences, Bengaluru.