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    • Self-assembly of a Co(II) dimer through H-bonding of water molecules to a 3D open-framework structure

      Sujit K Ghosh Parimal K Bharadwaj

      Volume 117 Issue 1 January 2005 pp 23-26

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/117/01/0023-0026

    • Keywords

       

      Metal-organic framework; hydrogen-bonding; aromatic polycarboxylate; Co(II) complex; crystal structure

    • Abstract

       

      Reaction of pyridine-2,4,6-tricarboxylic acid (ptcH3) with Co(NO3)2.6H2O in presence of 4,4′-bipyridine (4,4′-bpy) in water at room temperature results in the formation of [Co2(ptcH)2(4,4′-bpy) (H2O)4]·2H2O, (1). The solid-state structure reveals that the compound is a dimeric Co(II) complex assembled to a 3D architecture via an intricate intra- and inter-molecular hydrogen-bonding interactions involving water molecules and carboxylate oxygens of the ligand ptcH2-. Crystal data: monoclinic, spacegroup P21/c, a = 11·441(5) å,b = 20·212(2) å,c = 7·020(5) å, Β = 103·77(5)°,V= 1576-7(1) å3,Z = 2,R1 = 00363,wR2 = 0·0856,S = 1·000.

    • Author Affiliations

       

      Sujit K Ghosh1 Parimal K Bharadwaj1

      1. Chemistry Department, Indian Institute of Technology, Kanpur - 208 016, India

    • Dates

       
      Published
      January 2005
      Manuscript received
      11 May 2004
      Manuscript revised
      14 December 2004

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