• Epoxidation and oxidation reactions using 1,4-butanediol dimethacrylate crosslinked polystyrene-supported tertiary butyl hydroperoxide

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/116/06/0319-0324

    • Keywords

       

      Polystyrene-supported reagent; t-butyl hydroperoxide; solid-phase organic reagent; recyclability; epoxidation; oxidation

    • Abstract

       

      1,4-Butanediol dimethacrylate (1,4-BDDMA) crosslinked polystyrene-supported t-butyl hydroperoxide was employed in the epoxidation of olefins and oxidation of alcohols to carbonyl compounds. The reagent proved to be successful as a recyclable solid phase organic reagent with as much or more efficiency when compared to its monomeric counterpart. The extent of reaction was found to be dependent on various reaction parameters like solvent, temperature, molar concentration and presence of catalyst.

    • Author Affiliations

       

      M S Sheela1 K Sreekumar2

      1. Department of Chemistry, University of Kerala, Kariavattom Campus, Thiruvananthapuram - 695 581, India
      2. Department of Applied Chemistry, Cochin University of Science and Technology, Kochi - 682 022, India
    • Dates

       
  • Journal of Chemical Sciences | News

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