• Application of refractive index mixing rules in binary systems of hexadecane and heptadecane withn-alkanols at different temperatures

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/115/02/0147-0154

    • Keywords

       

      Hexadecane; heptadecane; refractive index; Lorentz-Lorenz relation; Heller relation; Weiner relation; Gladstone-Dale relation

    • Abstract

       

      Density and refractive index have been experimentally determined for binary liquid mixtures of hexadecane and heptadecane with 1-butanol, 1-pentanol, 1-hexanol and 1-heptanol at 298.15, 308.15 and 318.15 K. A comparative study of Lorentz—Lorenz (L-L), Weiner (W) and Heller (H), and Gladstone-Dale (G-D) relations for predicting the refractive index of a liquid has been carried out to test their validity for the eight binaries over the entire mole fraction range of hexadecane and heptadecane at the three temperatures. Comparison of various mixing rules has been expressed in terms of average percentage deviation. The performance of the Lorentz-Lorenz and Heller relations is relatively better than that of the Weiner and Gladstone-Dale relations.

    • Author Affiliations

       

      Rita Mehra1

      1. Department of Pure and Applied Chemistry, Maharshi Dayanand Saraswati University, Ajmer - 305 009, India
    • Dates

       
  • Journal of Chemical Sciences | News

    • Editorial Note on Continuous Article Publication

      Posted on July 25, 2019

      Click here for Editorial Note on CAP Mode

© 2017-2019 Indian Academy of Sciences, Bengaluru.