• Hydrothermal synthesis of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)0.5[V0.324+V0.685+O2PO4{P(OH)2}0.44]0.44]

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      https://www.ias.ac.in/article/fulltext/jcsc/115/01/0033-0040

    • Keywords

       

      Vanadyl phosphate; hydrothermal synthesis; intercalation; single crystal structure

    • Abstract

       

      In this paper we report the hydrothermal synthesis and characterisation of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)0.5 [V0.324+V0.685+O2PO4P(OH)20.44]. The phase purity of the solid was established using powder X-ray diffraction, single crystal X-ray diffraction, TGA, DTA, FTIR, UV-Vis and magnetic susceptibility measurements. Crystal data: orthorhombic,Pnma,a = 90289,b = 8.8962 andc = 15.9813 Å,V = 1283.7Å3,Z = 8. The structure contains layers made of VO5 square pyramids and PO4 tetrahedra; adjacent layers are connected through disordered tetrahedral PO2(OH)2 units. Ethylenediammonium cations occupy cavities in between the layers.

    • Author Affiliations

       

      P Ayyappan1 Minakshi Asnani1 A Ramanan1 Y Piffard2

      1. Department of Chemistry, Indian Institute of Technology, New Delhi - 110 016, India
      2. Institut des Matériaux de Nantes, Laboratoire de Chimie des Solides, CNRS, University of Nantes, France
    • Dates

       
  • Journal of Chemical Sciences | News

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