• Catalytic effects of poly(methyl methacrylate)-supportedβ-diketone-linked palladium complexes in olefin oxidation

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/114/05/0481-0486

    • Keywords

       

      Palladium complexes; poly(methyl methacrylate) support; olefin oxidation; β-diketone-linked complexes

    • Abstract

       

      Poly(methyl methacrylate)-supportedβ-diketone-linked palladium complexes on refluxing with olefins at 70°C in methanol-water medium for 10 h afforded carbonyl compounds. The course of the reaction was found to be influenced by the degree of cross-linking of the polymer matrix and the structural environment of the ligand. The reaction is assumed to proceed through a hydroxy palladation intermediate. A suitable mechanism is also suggested.

    • Author Affiliations

       

      Vipin A Nair1 M M Suni1 K Sreekumar2

      1. Department of Pharmaceutical Sciences, University of Tennessee, 847 Monroe Avenue, RM 327, Memphis, TN - 38163, USA
      2. Department of Applied Chemistry, Cochin University of Science and Technology, Cochin - 682 022, India
    • Dates

       
  • Journal of Chemical Sciences | News

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