• Copper(II) complexes with aroylhydrazones

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      https://www.ias.ac.in/article/fulltext/jcsc/114/04/0417-0430

    • Keywords

       

      Copper(II) complexes; aroylhydrazones; crystal structures; intermolecular interactions; self-assembly; magnetic properties; imine to imidate transformation

    • Abstract

       

      The coordination chemistry of copper(II) with tridentate aroylhydrazones is briefly discussed in this article. Two types of aroylhydrazones derived from aroylhydrazines and ortho-hydroxy aldehydes or 2-pyridine-carboxaldehyde have been used. The characterization of the complexes has been performed with the help of various physico-chemical techniques. Solid state structural patterns have been established by X-ray crystallography. In the solid state, structural varieties of these complexes are seen to range from monomeric, dimeric, polymeric and one-dimensional self-assembly via hydrogen bonds and π-π interactions. EPR spectroscopy and variable temperature magnetic susceptibility measurements have been used to reveal the nature of the coordination geometry and magnetic characteristics of these complexes.

    • Author Affiliations

       

      Samudranil Pal1

      1. School of Chemistry, University of Hyderabad, Hyderabad - 500 046, India
    • Dates

       
  • Journal of Chemical Sciences | News

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