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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/114/04/0367-0377

    • Keywords

       

      Pentacoordinate phosphorus; Phosphates; Hydrogen bonding; Cycloaddition; macrocycles; Phosphonates

    • Abstract

       

      The compounds [CH2(6-t-Bu-4-Me-C6H2O)2]PCl (1), (OCH2CMe2CH2O)-PCl (2), and [ClPN(t-Bu)]2 (3) have been utilized as precursors in the synthesis of (i) new pentacoordinate phosphorus compounds [e.g. CH2(6-t-Bu-4-Me-C6H2O)2 P(NRR′)(O2C6C14), CH2(6-t-Bu-4-Me-C6H2O)2PX[OC(O-i-Pr)N=N(C(O)O-i-Pr)],(ii) cyclic phosphates and their complexes [e.g. imidazolium+CH2(6-t-Bu-4-Me-C6H2O)2PO2-.MeOH], (iii) new cycloaddition products [e.g. CH2(6-t-Bu-4-Me-C6H2O)2PC(CO2Me)C(CO2Me)C(O)N, (iv) macrocyclic compounds [e.g. [(t-BuN)P]2[-OCH2CMe2CH2O-]h2] and (v) phosphonates [e.g. (OCH2CMe2CH2O)P (O)CH2C(CN)=CHC5H4FeC5H5]. The synthetic and structural aspects of these new products are discussed.

    • Author Affiliations

       

      K C Kumaraswamy1 Sudha Kumaraswamy1 Praveen Kommana1 N Satish Kumar1 K Senthil Kumar1

      1. School of Chemistry, University of Hyderabad, Hyderabad - 500 046, India

    • Dates

       
      Published
      August 2002

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