• Mixed ligand complex formation of FeIII with boric acid and typical N-donor multidentate ligands

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      https://www.ias.ac.in/article/fulltext/jcsc/114/03/0163-0174

    • Keywords

       

      Mixed ligand-FeIII-borate complexes; complex equilibria; N-donor multidentate ligands

    • Abstract

       

      Equilibrium study of the mixed ligand complex formation of FeIII with boric acid in the absence and in the presence of 2,2′-bipyridine, 1,10-phenanthroline, diethylenetriamine and triethylenetetramine (L) in different molar ratios provides evidence of formation of Fe(OH)2+, Fe(OH)2+ , Fe(L)3+, Fe(H2BO4),Fe(OH)(H2BO4), Fe(OH)2(H2BO4)2-, Fe(L)(H2BO4) and Fe2(L)2(BO4)+ complexes. Fe(L)23+, Fe(L)2(H2BO4) and Fe2(L)4(BO4)+ complexes are also indicated with 2,2′-bipyridine and 1,10-phenanthroline. Complex formation equilibria and stability constants of the complexes at 25 ± 0.l°C in aqueous solution at a fixed ionic strength,I = 0.1 mol dm-3 (NaNO3) have been determined by potentiometric method.

    • Author Affiliations

       

      G N Mukherjee1 Ansuman Das1

      1. Department of Chemistry, Calcutta University, University College of Science, 92, Acharya Prafulla Chandra Road, Kolkata - 700 009, India
    • Dates

       
  • Journal of Chemical Sciences | News

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