• A new layered iron fluorophosphate

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      https://www.ias.ac.in/article/fulltext/jcsc/114/02/0093-0105

    • Keywords

       

      Open-framework materials; layered iron phosphate; hydrothermal synthesis

    • Abstract

       

      A new iron fluorophosphate of the composition, [C6N4H21] [Fe2F2(HPO4)3][H2PO4]·2H2O,I has been prepared by the hydrothermal route. This compound contains iron fluorophosphate layers and the H2PO4- anions are present in the interlayer space along with the protonated amine and water molecules. The compound crystallizes in the monoclinic space group P21/c.(a = 13.4422(10) Å,b = 9.7320(10) Å, c = 18.3123(3) Å, β= 92.1480°,V= 2393.92(5) Å3, Z = 4,M = 719.92,dcalc. = 1.997 g cm-3, R1 = 0.03 andwR2= 0.09).

    • Author Affiliations

       

      Amitava Choudhury1 2

      1. Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur PO, Bangalore - 560 064, India
      2. Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore - 560 012, India
    • Dates

       
  • Journal of Chemical Sciences | News

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