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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/113/01/0063-0076

    • Keywords

       

      Cupronickels; passivation; solid-state model; cyclic voltammetry; marine environment

    • Abstract

       

      Cupronickels offer enhanced corrosion protection in marine environments by the formation of passive films on the surface. Cyclic voltammetric studies were carried on cupronickels in chloride solutions at pH 6.3 to understand the role of chloride ions in passive film formation. Increase in nickel content of the alloy and of chloride ions in solution decreases film resistance. Chloride ions take part in reduction of the passive film to copper. A solid-state model for passive film formation involving chloride ions has been attempted.

    • Author Affiliations

       

      J Mathiyarasu1 N Palaniswamy1 V S Muralidharan1

      1. Corrosion Science and Engineering Division, Central Electrochemical Research Institute, Karaikudi - 630 006, India
    • Dates

       
  • Journal of Chemical Sciences | News

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