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    • Synthesis of cyano-bridged bimetallic complexes of η5-indenyl ruthenium(II): Characterization and spectroscopic studies

      K Mohan Rao E K Rymmai

      Volume 113 Issue 1 February 2001 pp 29-33

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/113/01/0029-0033

    • Keywords

       

      Cyano-bridged; η5-indenyl; bimetallic complexes; ruthenium

    • Abstract

       

      Reactions of the cyanide complexes of the type [(Ind)Ru(PPh3)2CN] (1), [(Ind)Ru(dppe)CN] (2), [(Cp)Ru(PPh3)2CN] (3), with the corresponding chloro complexes [(Ind)Ru(PPh3)2Cl] (4), [(Ind)Ru(dppe)Cl] (5), [(Cp)Ru(PPh3)2Cl] (6), in the presence of NH4PF6 salt give homometallic cyano-bridged compounds of the type [(Ind)(PPh3)2Ru-CN-Ru(PPh3)2(Cp)]PF6 (7), [(Ind)(PPh3)2Ru-CN-Ru(PPh3)2(Ind)] PF6 where Ind = indenyl, η5-C9H7, (8), [(Cp)(PPh3)2Ru-CN-Ru(dppe)(Ind)]PF6, dppe = (Ph2PCH2CH2PPh2) (9), [(Ind(dppe)Ru-CN-Ru(PPh3)2(Ind)PF6 (10) and [(Ind)(dppe)Ru-CN-Ru(PPh3)2(Cp)]PF6 (11) respectively. Reaction of complex3 with [(p-cymene)RuCl2]2 dimer gave a mixed dimeric complex [(Cp)Ru(PPh3)2-CN-RuCl2(p-cymene)] (12). All these complexes have been characterized by IR,1H,13C and31P NMR spectroscopy and C, H, N analyses.

    • Author Affiliations

       

      K Mohan Rao1 E K Rymmai1

      1. Department of Chemistry, North Eastern Hill University, Shillong - 793 022, India

    • Dates

       
      Published
      February 2001
      Manuscript received
      7 September 2000
      Manuscript revised
      13 November 2000

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