• An overview on the applications of ‘Doyle catalysts’ in asymmetric cyclopropanation, cyclopropenation and C-H insertion reactions

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    • Keywords


      Doyle catalysts; asymmetric cyclopropanation; cyclopropenation; chiral catalysis; C-H insertions; chiral methyl phenidate

    • Abstract


      The chiral dirhodium(II) carboxamidates are a unique class of chiral catalysts useful for asymmetric inter- and intramolecular cyclopropanation, cyclopropenation and C-H insertion reactions with excellent enantioselectivities. The broad applications of these catalysts in organic syntheses are briefly reviewed.

    • Author Affiliations


      Thomas J Colacot1

      1. Organometallic Chemicals and Catalysts Development, Johnson Matthey, 2001 Nolte Drive, West Deptford, NJ - 08066, USA
    • Dates

  • Journal of Chemical Sciences | News

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      Posted on July 25, 2019

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