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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/112/03/0171-0178

    • Keywords

       

      Silanols; metallasiloxanes; hydrogen bonding; phosphonates; metal clusters

    • Abstract

       

      This article presents a brief overview of different kinds of silanols and the important reactions of N-bonded silanetriols. The synthesis and characterization of silanediols containing Si-N and Si-C bonds, (2,4,6-Me3C6H2)N(SiMe3)Si(Me)(OH)2 (1e) is described. 1e shows a polymeric crinkled tape type of structure due to extensive intermolecular hydrogen bonding. We also describe the formation of a neutral copper(II) complex derived from the reaction of CuCl2 with (O)P(3,5-Me2Pz)3 where the ligand undergoes a facile P-N bond cleavage and functions as an N2O type of tridentate ligand.

    • Author Affiliations

       

      V Chandrasekhar1 S Nagendran1 S Kingsley1 V Krishnan1 R Boomishankar1

      1. Department of Chemistry, Indian Institute of Technology, Kanpur - 208 016, India

    • Dates

       
      Published
      June 2000

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