• Synthesis and characterization of the complexes of some transition metals with 2-acetyl pyridine (N-benzoyl) glycyl hydrazone

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      https://www.ias.ac.in/article/fulltext/jcsc/111/05/0615-0626

    • Keywords

       

      Transition complexes; 2-acetylpyridine (N-benzoyl)glycyl hydrazone; isomer; tridentate ligand

    • Abstract

       

      Complexes of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) with 2-acetyl pyridine (N-benzoyl) glycyl hydrazone(2-ApBzGH) have been synthesized and characterized by elemental analyses, molar conductances, magnetic susceptibility, IR, electronic, ESR,1H,13C and113Cd NMR spectral and X-ray diffraction studies. IR and NMR data suggest the tridentate nature of the ligand coordinating as a neutral species in the addition complexes and as a uninegative species in the deprotonated complexes. The presence of more than one isomer of the ligand has been established by1H NMR spectra of the ligand and complexes recorded over the 298–396 K range. The X-ray powder diffraction patterns of [Cd(2-ApBzGH)Cl]Cl and [Cu(2-ApBzGH)Cl(H2O)2]Cl are indexed for orthorhombic and tetragonal crystal systems respectively.

    • Author Affiliations

       

      R K Lonibala1 T R Rao2

      1. Chemistry Department, Manipur University, Canchipur - 795 003, India
      2. Department of Chemistry, Banaras Hindu University, Varanasi - 221 005, India
    • Dates

       
  • Journal of Chemical Sciences | News

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