• Oxo-metal complexes of alkoxo rich ligands and reactivity of vanadium complexes

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/111/03/0479-0487

    • Keywords

       

      Vanadium complexes; NMR spectra; catalytic nature; bromination reaction

    • Abstract

       

      Oxo-metal centers, such as, VO3+,cis-VO2+,cis-MoO22+ andtrans-UO22+ exhibited different coordination geometries and charge types to result in totally nine different types of structures, all of which were characterized by single crystal X-ray diffraction. Aqueous stability, reactivity towards acid, H2O2 and bromide of vanadium complexes are studied using absorption and51V NMR spectra. Catalytic nature of the bromination reaction by vanadium complexes has also been addressed.

    • Author Affiliations

       

      Chebrolu P Rao1 A Sreedhara1

      1. Bioinorganic Laboratory, Department of Chemistry, Indian Institute of Technology Bombay, Mumbai - 400 076, India
    • Dates

       
  • Journal of Chemical Sciences | News

© 2021-2022 Indian Academy of Sciences, Bengaluru.