• New organometallic chemistry of ruthenium and osmium

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/111/03/0469-0477

    • Keywords

       

      Organometallics; decarbonylative orthometalation; iminium-phenolato zwitterion; conformational tautomerisation; alkyne insertion

    • Abstract

       

      The reaction of Schiff monobases of 2,6-diformyl-4-methylphenol with ruthenium(II) and osmium(II) has afforded a new family of orthometalated organometallics. Synthesis, characterization and reactivity are briefly discussed in this article.

    • Author Affiliations

       

      Animesh Chakravorty1 2

      1. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Calcutta - 700 032, India
      2. Jawaharlal Nehru Centre for Advanced Scientific Research, Indian Institute of Science Campus, Bangalore - 560 012, India
    • Dates

       
  • Journal of Chemical Sciences | News

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