• Salicylaldoxime: An old ligand with new faces

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    • Keywords


      Salicylaldoxime; transition metal ions; polynuclear complexes; magnetochemistry; spin frustration

    • Abstract


      The paper is concerned with the interactions of salicylaldoxime with trivalent transition metal ions to yield di-, tri-, tetra- and hexanuclear complexes together with their low-lying electronic structures. Tri- and tetranuclear complexes are found to exhibit spin frustration. The importance of isostructural series of compounds with varyingdn electron configurations is indicated. Relevance of some of these compounds as models for metalloproteins is also shown.

    • Author Affiliations


      Phalguni Chaudhuri1

      1. Max-Planck-Institut für Strahlenchemie, Mülheim an der Ruhr - D-45470, Germany
    • Dates

  • Journal of Chemical Sciences | News

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