• Reactions ofη5-cyclopentadienylruthenium(II) complexes withγ-hydroxyacetylenes

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/108/04/0351-0360

    • Keywords

       

      γ-Hydroxyacetylenes; vinylidenes; allenylidenes; cyclopentadiene

    • Abstract

       

      The complexes [CpRuL2Cl] (L=PPh3, AsPh3, SbPh3) react with the phenylacetylene,γ-hydroxyacetylenes HC≡CCR1R2OH (R1=R2=H, Me, and R1=Me, R2=Et; CR1R2OH=1-hydroxycyclohexanol) and NaBF4 in methanol, to yield complexes of the typeη1-vinylidenes [CpL2Ru+(=C=CHR)],η1- allenylidene [CpL2Ru+ (=C=C=CR1R2)], and dimeric allenylidene-vinyl and vinylidene-alkylidene complexes. Theseη1-vinylidene andη1-allenylidene complexes are reversibly deprotonated by sodium borohydride in methanol to yield the correspondingη1-alkynyl complexes [CpL2Ru(C≡CR)].

    • Author Affiliations

       

      K Mohan Rao1 2 U C Agarwala1 3

      1. Department of Chemistry, Indian Institute of Technology, Kanpur - 208 016, India
      2. 295A, C-1, Indira Nagar, Kanpur - 208 026, India
      3. School of Chemistry, University of Hyderabad, Hyderabad - 500 046, India
    • Dates

       
  • Journal of Chemical Sciences | News

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