• Oxidation of substituted benzylic hydrocarbons and naphthalenes by peroxydisulphate in the presence of metal ions

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      https://www.ias.ac.in/article/fulltext/jcsc/107/05/0567-0572

    • Keywords

       

      Metal ion catalysed oxidation; benzylic hydrocarbons; substituted naphthalenes and potassium peroxydisulphate

    • Abstract

       

      Oxidations of various substituted benzylic hydrocarbons with peroxydisulphate in the presence of metal ion catalysts like iron, nickel, copper, cobalt, silver and cerium were examined. Among the metal ions copper (II) catalysed reaction gives products in excellent yield, whereas oxidation of naphthalene and substituted naphthalenes gives low to moderate yield of the products with peroxydisulphate — copper (II).

    • Author Affiliations

       

      P Thirumalai Perumal1 2 M Vivekananda Bhatt1

      1. Department of Organic Chemistry, Indian Institute of Science, Bangalore - 560 012, India
      2. Organic Division, Central Leather Research Institute, Adyar, Madras - 600 020, India
    • Dates

       
  • Journal of Chemical Sciences | News

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