• Studies on 2-acetylpyridineisonicotinoyl hydrazone complexes of some bivalent 3d-metal ions

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      https://www.ias.ac.in/article/fulltext/jcsc/107/01/0025-0033

    • Keywords

       

      2-Acetylpyridineisonicotinoyl hydrazone complexes; 3d-metal complexes; unsymmetrical Schiff-base complexes

    • Abstract

       

      2-Acetylpyridineisonicotinoyl hydrazone (Hapinh) complexes of OV(II), Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) having 1:1 metal-ligand stoichiometry have been prepared and characterised by elemental analyses, molar conductance, magnetic susceptibility, electronic, infrared, ESR and NMR (1H and13C) studies. Octahedral/distorted octahedral geometry has been assigned for the OV(II), Mn(II), Ni(II), Cu(II) and Zn(II) complexes while tetrahedral and trigonal bipyramidal configurations have been suggested for the Co (II) adduct and deprotonated complexes respectively. IR and NMR spectral studies suggest a tridentate behaviour of Hapinh and apinh species in the adducts and deprotonated complexes respectively.

    • Author Affiliations

       

      Pariti S S J Sastry1 T R Rao1

      1. Department of Chemistry, Banaras Hindu University, Varanasi - 221005, India
    • Dates

       
  • Journal of Chemical Sciences | News

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