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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/106/01/0045-0048

    • Keywords

       

      Pheromones; (Z)-7-hexadecen-1-yl acetate; (Z)-7-hexadecenal

    • Abstract

       

      Alkylation of 1-bromo-6-tetrahydropyranyloxyhexane with the dianion of 4-pentyn-1-ol yielded 11-tetrahydropyranyloxy-4-undecyn-1-ol (4) which upon catalytic hydrogenation and subsequent mesylation afforded (6). Li2CuCl4 catalysed the coupling of (6) with pentylmagnesium bromide gave 1-(tetrahydropyranyloxy)-7(Z)-hexadecene (8) which on depyranylation resulted in (Z)-7-hexadecen-1-ol (9). The alcohol (9) was then converted into the corresponding target compounds, (Z)-7-hexadecen-1-yl acetate (1) and (Z)-7-hexadecenal (2).

    • Author Affiliations

       

      M L Sharma1 Tek Chand1 Sadhana Verma1

      1. Department of Chemistry, Panjab University, Chandigarh - 160 014, India
    • Dates

       
  • Journal of Chemical Sciences | News

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