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    • Sulphur-bonded thallous complexes of thiosemicarbazones

      N C Bhardwaj R V Singh

      Inorganic and Analytical Volume 106 Issue 1 February 1994 pp 15-22

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/106/01/0015-0022

    • Keywords

       

      Thallium (I) compounds; thiosemicarbazones; heterocyclic moiety; spectral studies; monobasic bidentate ligand

    • Abstract

       

      An interesting series of some sulphur-bonded unusual bicoordinated thallium(I) complexes of the type TIL (where L is the anion of a monobasic bidentate thiosemicarbazone) has been obtained by the equimolar reactions of thallous chloride with the sodium salt of the ligands (thiosemicarbazones) derived from the condensation of heterocyclic aldehydes or ketones with thiosemicarbazide. The complexes have been characterized by elemental analyses, conductance measurements, molecular weight determinations and electronic, IR,1H and13C NMR spectral studies.

    • Author Affiliations

       

      N C Bhardwaj1 R V Singh1

      1. Department of Chemistry, University of Rajasthan, Jaipur - 302 004, India

    • Dates

       
      Published
      February 1994
      Manuscript received
      16 June 1993
      Manuscript revised
      27 October 1993

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