• Molecular structure of electron donor-acceptor complexes of metallotetraphenylporphyrins with trinitrobenzene

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/105/03/0161-0165

    • Keywords

       

      Electron donor-acceptor complexes; structural parameters; charge-transfer interactions; metallotetraphenylporphyrins; trinitrobenzene acceptor

    • Abstract

       

      The metallotetraphenylporphyrins, MTPPs, where M=Co(II), Cu(II) and Ag(II) form one to one molecular complexes in solution with 1,3,5-trinitrobenzene (TNB). The crystal structure of CoTPP.TNB.2CH3OH revealed that the mean separation between the porphyrin and TNB planes is 3·27 Å and the centre of the aryl ring of TNB is displaced by 0·90 Å from the centre of the porphyrin plane. Extended Huckel molecular orbital calculations suggest that acceptor orbitals are predominantly nitro-group based rather than an aryl π framework. The contribution of the metal orbitals in the donation is also seen as predicted by the structural data. Electrochemical redox measurements in solution provide evidence for charge-transfer stabilisation in these complexes.

    • Author Affiliations

       

      M Padmanabhan1 M Damodara Poojari1 V Krishnan1

      1. Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore - 560 012, India
    • Dates

       
  • Journal of Chemical Sciences | News

© 2021-2022 Indian Academy of Sciences, Bengaluru.