• Pulse radiolysis of some aromatic sulphoxides in aqueous solutions

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/105/02/0141-0147

    • Keywords

       

      Pulse radiolysis; aromatic sulphoxides; transients

    • Abstract

       

      Reactions ofeaq and H-atoms with aromatic sulphoxides such as dibenzyl, diphenyl and di-4-chlorophenyl sulphoxides have been studied at various pH values and the spectral and kinetic properties of the transients determined.eaq addition to dibenzyl sulphoxide was found to lead to the scission of the C−S bond giving benzyl radicals, but such bond breakage was not observed in other cases.

    • Author Affiliations

       

      K Kishore1 G R Dey1 P N Moorthy1

      1. Applied Chemistry Division, Bhabha Atomic Research Centre, Trombay, Bombay - 400 085, India
    • Dates

       
  • Journal of Chemical Sciences | News

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