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    • Pulse radiolysis of some aromatic sulphoxides in aqueous solutions

      K Kishore G R Dey P N Moorthy

      Physical and Theoretical Volume 105 Issue 2 April 1993 pp 141-147

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/105/02/0141-0147

    • Keywords

       

      Pulse radiolysis; aromatic sulphoxides; transients

    • Abstract

       

      Reactions ofeaq− and H-atoms with aromatic sulphoxides such as dibenzyl, diphenyl and di-4-chlorophenyl sulphoxides have been studied at various pH values and the spectral and kinetic properties of the transients determined.eaq− addition to dibenzyl sulphoxide was found to lead to the scission of the C−S bond giving benzyl radicals, but such bond breakage was not observed in other cases.

    • Author Affiliations

       

      K Kishore1 G R Dey1 P N Moorthy1

      1. Applied Chemistry Division, Bhabha Atomic Research Centre, Trombay, Bombay - 400 085, India

    • Dates

       
      Published
      April 1993
      Manuscript received
      27 July 1992
      Manuscript revised
      30 October 1992

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