• Complexes of N, S donor ligands. CoII, CoIII, MnIII, FeIII and PdII complexes of 1, 2-di(o-aminophenylthio)ethane: Synthesis, characterisation and reactions

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      https://www.ias.ac.in/article/fulltext/jcsc/105/01/0001-0009

    • Keywords

       

      Diamino-dithioether; macrocycle; Curtis reaction

    • Abstract

       

      The ligand 1,2-di(o-aminophenylthio)ethane (abbreviated as H2DAPTE) has been allowed to react with various metal salts and the complexes isolated and characterised. In these complexes, H2 DAPTE behaves as a neutral quadridentate and also as a dibasic quadridentate ligand after losing two protons from the amine functions. Two complexes of this ligand, reported earlier, have been condensed with acetone to form macrocyclic complexes of TDDH where TDDH is 13, 13, 15-trimethy1-2,5-dithia-12, 16-diazatricyclo-[15,3,0,0,6,11]-docosa-1(17), 6(11), 7,9,15,18,20-heptene.

    • Author Affiliations

       

      G Mukherjee1 S Pal1 S N Poddar1 K Dey1 2

      1. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Calcutta - 700032, India
      2. Department of Chemistry, Kalyani University, Kalyani - 741 235, India
    • Dates

       
  • Journal of Chemical Sciences | News

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