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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/104/05/0569-0576

    • Keywords

       

      Ring-transformation; sensitization; fluorescence; SHELXTL program

    • Abstract

       

      Sunlight photolysis of 4,5-diphenylisoxazole (1) in methanol sensitized by benzophenone gives 4,4′,5,5′-tetraphenyl-2,2′-bioxazole, (4). On irradiation at 350nm in acetone or at 253.7 nm in absolute alcohol, isoxazole (1) yields α-benzoylphenylacetonitrile (6) besides the expected phenanthro [9,10-d]-oxazole (5). The bioxazole and the ketonitrile have been identified by single crystal X-ray studies.

    • Author Affiliations

       

      V Keshava Rao1 T Jaganmohana Chary1 A Krishna Murthy1

      1. Department of Chemistry, Kakatiya University, Warangal - 506009, India
    • Dates

       
  • Journal of Chemical Sciences | News

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