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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/104/05/0535-0542

    • Keywords

       

      Cytochrome C; polyaminoacids; infrared and ESCA data; hydrogenation catalyst

    • Abstract

       

      Polyamino acids (amino acid = valine, alanine, lysine and arginine) and the protein cytochrome C (Cyt C) have been treated with [Rh(CO)2Cl]2 (1) to give polymersupportedcis-dicarbonyl species. The polymer-supported rhodium complexes, characterised on the basis of infrared and ESCA data, have been found to undergo reversible decarbonylation reaction. The Cyt C-supported rhodium complex acts as a hydrogenation catalyst of low to moderate activity. In the hydrogenation of 3-methyl cyclohexanone no stereoselectivity has been observed.

    • Author Affiliations

       

      Krishna Sharma1 Vishnu S Darshane1 Periyakaruppan T Manoharan2 S Bhaduri3

      1. The Institute of Science, 15, Madam Cama Road, Bombay - 400032, India
      2. Indian Institute of Technology, Madras - 600036, India
      3. Alchemie Research Centre, Thane-Belapur Road, P O Box 155, Thane - 400601, India
    • Dates

       
  • Journal of Chemical Sciences | News

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