• CNDO/II treatment of proton abstraction step in aromatic lithiation reaction

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/104/03/0425-0429

    • Keywords

       

      CNDO/II calculation; charge ono-hydrogen

    • Abstract

       

      All valence MO calculation employing CNDO/II treatment for hydrogen abstraction step in aromatic ortho lithiation reaction is done. The predicted proton abstraction is supported by experimental observation. The lithiation of N-methyl-β-naphthamide occurs at the 1 position and not at the 3 position.

    • Author Affiliations

       

      B H Bhide1 V G Prabhu1 Arabinda Ray1

      1. Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar - 388 120, India
    • Dates

       
  • Journal of Chemical Sciences | News

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