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    • Keywords


      Zero-field splittings; Zn(II)-mixed-ligand complexes; LLCT emitting states

    • Abstract


      Zero-field splittings of the emitting levels of the title compounds were measured by ODMR. For complexes of the type Zn(X-PhS)2(phen) resonances of the3ππ* phosphorescing levels were observed for X=F5, 4-Cl, 4-CH3. For X=4-Cl, resonances were detected for the3LLCT emitting manifold also. For X=4-CH3O, resonances were detected only for the3LLCT emitting states. A model invoking mixing between the two types of states is proposed that satisfactorily accounts for the dependences of the properties of the emitting manifolds on the donating ability of the X substituent.

    • Author Affiliations


      Kaoru Nozaki1 Shigeru Ikeda1 Seiichi Yamamoto1 Takeshi Ikeyama1 2 Tohru Azumi1 J A Burt3 G A Crosby3

      1. Department of Chemistry, Faculty of Science, Tohoku University, Sendai - 980, Japan
      2. Present address: Department of Chemistry, Miyagi University of Education, Sendai - 980, Japan
      3. Department of Chemistry, Washington State University, Pullman, Washington - 99164-4630, USA
    • Dates

  • Journal of Chemical Sciences | News

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