• Oxidation of primary amines with dioxygen catalysed by an oxygen carrier cobalt(II) Schiff base chelate, CoSMDPT

    • Fulltext

       

        Click here to view fulltext PDF


      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/103/06/0741-0745

    • Keywords

       

      Dioxygen; oxidation of primary amines; cobalt(II)bis[3-(salicylideneamino) propyl] methylamine

    • Abstract

       

      Cobalt(II)bis[3-(salicylideneamino) propyl] methylamine, (CoSMDPT) catalysed the oxidation of primary amines with dioxygen. The oxidation of benzylamine, 4-methyl-benzylamine and 4-methoxybenzylamine gave aldehyde intermediates which reacted with the starting amines to yield the corresponding Schiff bases as the final products. The oxidation of 1-phenylethylamine gave 2,4,6-triphenyl-3-aza-3,5-heptadiene by disproportionation of the intermediate Schiff base, 2,4-diphenyl-3-aza-3-heptene.

    • Author Affiliations

       

      Prahlad A Ganeshpure1 A Sudalai1 Sheo Satish1

      1. Research Centre, Indian Petrochemicals Corporation Limited, Vadodara - 391 346, India
    • Dates

       
  • Journal of Chemical Sciences | News

© 2021-2022 Indian Academy of Sciences, Bengaluru.