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    • Studies on salicylaldehyde-2-aminobenzophenone-2-thenoylhydrazone complexes with 3d metal ions

      B Singh A K Srivastav

      Volume 103 Issue 6 December 1991 pp 691-699

    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/103/06/0691-0699

    • Keywords

       

      Salicyladehyde-2-aminobenzophenone-2-thenoylhydrazone; transition metal complexes; square pyramidal geometry; octahedral geometry

    • Abstract

       

      Salicylaldehyde-2-aminobenzophenone-2-thenoylhydrazone (Hsabth) complexes of OV(IV), Mn(II), Ni(II), Ni(II), Cu(II) and Zn(II) having 1∶2 metal-ligand stoichiometry have been prepared and characterized by elemental analyses, molar conductance, magnetic susceptibility, electronic, ESR, infrared, NMR (1H and13C) and X-ray powder diffraction studies. Square pyramidal geometry around oxovandium(IV) and octahedral geometry around the rest of the metal ions have been proposed on the basis of magnetic and spectral studies.

    • Author Affiliations

       

      B Singh1 A K Srivastav1

      1. Department of Chemistry, Banaras Hindu University, Varanasi - 221 005, India

    • Dates

       
      Published
      December 1991
      Manuscript received
      14 August 1990
      Manuscript revised
      22 March 1991

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