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    • Fulltext

       

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/103/03/0499-0503

    • Keywords

       

      Reaction kinetics; OH radicals; cycloalkanes

    • Abstract

       

      A laser flash photolysis/resonance fluorescence investigation has been carried out to study the kinetics of the overall reactions OH + cyclopropane (1) and OH + cyclobutane (2) in the temperature range 298–490 K and at 298 K, respectively. The following kinetic parameters have been determined: k1 =(3.9 ±0.6) 10−12exp- (2.2 ± 0.1)kcal mol−1/RT molecule−1cm3s−1, k2(298 K) = (17.5 ± 1.5)10−13molecule−1 cm3s−1.

    • Author Affiliations

       

      S Dóbé1 T Turányi1 T Bérces1 F Márta1

      1. Central Research Institute for Chemistry, Hungarian Academy of Science, P.O. Box 17, Budapest - H-1525, Hungary

    • Dates

       
      Published
      March 1991

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