• Polystyrene anchored rhodium (I) bidentate ligand complexes as catalysts for hydrogenation

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/103/02/0099-0106

    • Keywords

       

      Polymer-anchored Rh(I) catalyst; bidentate ligand; rate law

    • Abstract

       

      Polystyrene supported Rh(I) AA′ (AA′ = anthranilic acid, 2,2′-bipyridine or 1,10-phenanthroline) complexes catalyse the hydrogenation of monoolefins (terminal, cyclic and internal) and dienes. Ethyl sorbate undergoes saturation via the monoene intermediate. Thiscis olefin reacts faster than thetrans isomer. The rate law for the reaction is: Rate α [catalyst] [substrate] [H2].

    • Author Affiliations

       

      V R Parameswaran1 S Vancheesan1

      1. Department of Chemistry, Indian Institute of Technology, Madras - 600036, India
    • Dates

       
  • Journal of Chemical Sciences | News

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