• Hydrogenation of olefinic substrates in aqueous and aqueous-organic biphase systems using rhodium complex of sulphonated triphenyl phosphine

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      https://www.ias.ac.in/article/fulltext/jcsc/103/01/0001-0007

    • Keywords

       

      Water soluble Rh(I) complex; homogeneous hydrogenation; rate law

    • Abstract

       

      Water-soluble meta sulphophenyldiphenylphosphine complex of rhodium preparedin situ catalyses the homogeneous hydrogenation of fumaric, maleic and crotonic acids in water and 1:1 water-methanol mixture as solvents. Fumaric acid gives a higher rate of hydrogenation than maleic acid. Rate of hydrogenation also increases on changing the solvent from pure water to 1:1 mixture of methanol and water. Rate law for the reaction has been proposed.

    • Author Affiliations

       

      V R Parameswaran1 S Vancheesan1

      1. Department of Chemistry, Indian Institute of Technology, Madras - 600036, India
    • Dates

       
  • Journal of Chemical Sciences | News

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