• Diethylenetriaminebis(dithiocarbamate) derivatives of some first row transition metals

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      https://www.ias.ac.in/article/fulltext/jcsc/102/06/0725-0730

    • Keywords

       

      Diethylenetriaminebis(dithiocarbamate); magnetic moment; reflectance spectra; ESR spectra; infrared spectra

    • Abstract

       

      Cr(III), Fe(III), Co(II), Ni(II) and Cu(II) complexes of diethylenetriaminebis(dithiocarbamate), L, have been synthesized and characterized by elemental analysis, magnetic measurements, electronic, esr and infrared spectral studies. The Cr(III) and Fe(III) complexes are octahedral with composition [M(L)(H20)Cl], whereas Co(II), Ni(II) and Cu(II) derivatives, [CoL]·2H20, [NiL] and [CuL], are square-planar. The esr spectral features indicate significant distortion from ideal symmetry.

    • Author Affiliations

       

      P K Gogoi1 D P Phukan1

      1. Department of Chemistry, Dibrugarh University, Dibrugarh - 786004, India
    • Dates

       
  • Journal of Chemical Sciences | News

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