• Study of the effect of nature of ligand on reproportionation constants of ternary complexes

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      Permanent link:
      https://www.ias.ac.in/article/fulltext/jcsc/102/04/0513-0519

    • Keywords

       

      Reproportionation constant; ternary complexes; nature of ligand

    • Abstract

       

      The stability constants of ternary M(II) complexes, [MLL′], where M refers to Cu(II) or Ni(II), L refers to ethylenediamine (en), 1,3-diaminopropane (1,3-pn), N,N-dimethylethylenediamine (N,N-dimen), N,N-diethylethylenediamine (N,N-dien) and L′ refers to catechol, catechuic acid, tiron, pyrogallol,o-aminophenol,o-phenylenediamine, oxalic acid, malonic acid, glycine, α-alanine, β-alanine, have been determined potentiometrically using the SCOGS computer program. LogKreprop. (reprop.-reproportionation) of ternary complexes have been calculated. The effecf of the nature of the ligand onKreprop. values has been discussed for these ternary complexes and the fact thatKreprop. is not a proper measure of the stability of the ternary complex has been indicated.

    • Author Affiliations

       

      M R Ullah1 P K Bhattacharya1

      1. Department of Chemistry, Faculty of Science, M S University of Baroda, Baroda - 390 002, India
    • Dates

       
  • Journal of Chemical Sciences | News

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