• Electron energy loss spectroscopic study of Cr(CO)6, Mo(CO)6 and W(CO)6 in the vapour phase

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      https://www.ias.ac.in/article/fulltext/jcsc/102/01/0001-0005

    • Keywords

       

      Electron energy loss spectra; transition metal hexacarbonyls; molecular energy level schemes

    • Abstract

       

      Electron energy loss spectra (EELS) of Cr, Mo and W hexacarbonyls in the vapour phase are reported. Most of the bands observed are similar to those in optical spectra, but the two high energy transitions in the 9·8–11·2 eV region are reported here for the first time. Based on the orbital energies from the ultraviolet photoelectron spectra and the electronic transition energies from EELS and earlier optical studies, the molecular energy level schemes of these molecules are constructed.

    • Author Affiliations

       

      T Pradeep1

      1. Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore - 560 012, India
    • Dates

       
  • Journal of Chemical Sciences | News

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