• Synthesis, characterization and chelating properties of poly [azo-(6-hydroxy-1,3-phenylene)]

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    • Keywords


      2,4-Dinitro phenol (DNP); poly [azo(6-hydroxy-1,3-phenylene)] (PAHP); polychelates of PAHP

    • Abstract


      Poly [azo(6-hydroxy-1,3-phenylene)] (PAHP) was prepared by alcoholic alkaline reduction of 2,4-dinitro phenol (DNP). The polymers prepared at various time intervals were characterized by elemental analyses, IR spectra and thermogravimetric analysis. The number average molecular weight$$(\bar M_n )$$ was determined by non-aqueous titration. Viscometric study in DMF of all the three polymers were carried out and indicates polyelectrolyte behaviour. Viscometric study in DMF-water (85:15)(v/v) containing 1%KBr shows normal behaviour.

      Polymeric metal chelates of Cu2+, Ni2+, Co2+, Zn2+, Mn2+ and Cr2+ with PAHP polymer were prepared and characterized.

    • Author Affiliations


      Hasmukh S Patel1 Mahesh D Prajapati1

      1. Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar - 388 120, India
    • Dates

  • Journal of Chemical Sciences | News

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